The “greening” of industry processes, i.e. making them more sustainable, is a popular and often lucrative trend which has emerged over recent years. The 3rd volume of Green Chemical Processing considers sustainable chemistry in the context of corporate interests. The American Chemical Society’s 12 Principles of Green Chemistry are woven throughout this text as well as the series to which this book belongs.
Edited by three of the world's leading pharmaceutical scientists, this is the first book on this important and hot topic, containing much previously unpublished information. As such, it covers all aspects of green chemistry in the pharmaceutical industry, from simple molecules to complex proteins, and from drug discovery to the fate of pharmaceuticals in the environment. Furthermore, this ready reference contains several convincing case studies from industry, such as Taxol, Pregabalin and Crestor, illustrating how this multidisciplinary approach has yielded efficient and environmentally-friendly processes. Finally, a section on technology and tools highlights the advantages of green chemistry.
Sustainable development is now accepted as a necessary goal for achieving societal, economic and environmental objectives. Within this chemistry has a vital role to play. The chemical industry is successful but traditionally success has come at a heavy cost to the environment. The challenge for chemists and others is to develop new products, processes and services that achieve societal, economic and environmental benefits. This requires an approach that reduces the materials and energy intensity of chemical processes and products; minimises the dispersion of harmful chemicals in the environment; maximises the use of renewable resources and extends the durability and recyclability of products in a way that increases industrial competitiveness as well as improve its tarnished image.
The editors and authors, with backgrounds in academia and industry, tie together recent and established technologies for the upcoming change to sustainable industrial chemistry. The extensive worldwide activities towards that goal are exemplified with a series of green processes. Some of these processes are already commercially applied (squalene to squalane, hydraulic fluids from vegetable oils, biosourced polycarbonates), others are ready for a large scale implementation (glycerol to acrylic acid, biosourced acrylonitrile and levulinic acid, polyamides from fatty nitriles-esters hydrogenation, butadiene from bioethanol) or are being developed (cyclic carbonates from epoxides, selective pyrolysis of biomass). This book is an indispensable source for the researchers and professionals who work for a greener chemical industry. The chapters have been arranged to guide students through the design of new processes for more sustainable chemistry, using case studies as examples.
The editors and authors, with backgrounds in academia and industry, tie together recent and established technologies for the upcoming change to sustainable industrial chemistry. The extensive worldwide activities towards that goal are exemplified with a series of green processes. Some of these processes are already commercially applied (squalene to squalane, hydraulic fluids from vegetable oils, biosourced polycarbonates), others are ready for a large scale implementation (glycerol to acrylic acid, biosourced acrylonitrile and levulinic acid, polyamides from fatty nitriles-esters hydrogenation, butadiene from bioethanol) or are being developed (cyclic carbonates from epoxides, selective pyrolysis of biomass). This book is an indispensable source for the researchers and professionals who work for a greener chemical industry. The chapters have been arranged to guide students through the design of new processes for more sustainable chemistry, using case studies as examples.
Everyone is becoming more environmentally conscious and therefore, chemical processes are being developed with their environmental burden in mind. This also means that more traditional chemical methods are being replaced with new innovations and this includes new solvents. Solvents are everywhere, but how necessary are they? They are used in most areas including synthetic chemistry, analytical chemistry, pharmaceutical production and processing, the food and flavour industry and the materials and coatings sectors. However, the principles of green chemistry guide us to use less of them, or to use safer, more environmentally friendly solvents if they are essential. Therefore, we should always ask ourselves, do we really need a solvent? Green chemistry, as a relatively new sub-discipline, is a rapidly growing field of research. Alternative solvents - including supercritical fluids and room temperature ionic liquids - form a significant portion of research in green chemistry. This is in part due to the hazards of many conventional solvents (e.g. toxicity and flammability) and the significant contribution that solvents make to the waste generated in many chemical processes. Solvents are important in analytical chemistry, product purification, extraction and separation technologies, and also in the modification of materials. Therefore, in order to make chemistry more sustainable in these fields, a knowledge of alternative, greener solvents is important. This book, which is part of a green chemistry series, uses examples that tie in with the 12 principles of green chemistry e.g. atom efficient reactions in benign solvents and processing of renewable chemicals/materials in green solvents. Readers get an overview of the many different kinds of solvents, written in such a way to make the book appropriate to newcomers to the field and prepare them for the 'green choices' available. The book also removes some of the mystique associated with 'alternative solvent' choices and includes information on solvents in different fields of chemistry such as analytical and materials chemistry in addition to catalysis and synthesis. The latest research developments, not covered elsewhere, are included such as switchable solvents and biosolvents. Also, some important areas that are often overlooked are described such as naturally sourced solvents (including ethanol and ethyl lactate) and liquid polymers (including poly(ethyleneglycol) and poly(dimethylsiloxane)). As well as these additional alternative solvents being included, the book takes a more general approach to solvents, not just focusing on the use of solvents in synthetic chemistry. Applications of solvents in areas such as analysis are overviewed in addition to the more widely recognised uses of alternative solvents in organic synthesis. Unfortunately, as the book shows, there is no universal green solvent and readers must ascertain their best options based on prior chemistry, cost, environmental benefits and other factors. It is important to try and minimize the number of solvent changes in a chemical process and therefore, the importance of solvents in product purification, extraction and separation technologies are highlighted. The book is aimed at newcomers to the field whether research students beginning investigations towards their thesis or industrial researchers curious to find out if an alternative solvent would be suitable in their work.
Written by an expert, using the same approach that made the previous two editions so successful, Fundamentals of Environmental Chemistry, Third Edition expands the scope of book to include the strongly emerging areas broadly described as sustainability science and technology, including green chemistry and industrial ecology. The new edition includes: Increased emphasis on the applied aspects of environmental chemistry Hot topics such as global warming and biomass energy Integration of green chemistry and sustainability concepts throughout the text More and updated questions and answers, including some that require Internet research Lecturers Pack on CD-ROM with solutions manual, PowerPoint presentations, and chapter figures available upon qualifying course adoptions The book provides a basic course in chemical science, including the fundamentals of organic chemistry and biochemistry. The author uses real-life examples from environmetnal chemistry, green chemistry, and related areas while maintaining brevity and simplicity in his explanation of concepts. Building on this foundation, the book covers environmental chemistry, broadly defined to include sustainability aspects, green chemistry, industrial ecology, and related areas. These chapters are organized around the five environmental spheres, the hydrosphere, atmosphere, geosphere, biosphere, and the anthrosphere. The last two chapters discuss analytical chemistry and its relevance to environmental chemistry. Manahan’s clear, concise, and readable style makes the information accessible, regardless of the readers’ level of chemistry knowledge. He demystifies the material for those who need the basics of chemical science for their trade, profession, or study curriculum, as well as for readers who want to have an understanding of the fundamentals of sustainable chemistry in its crucial role in maintaining a livable planet.
The book gives a systematic introduction to green chemistry principles and technologies in inorganic and organic chemistry, polymer sciences and pharmaceutical industry. It also discusses the use of biomass and marine resources for synthesis as well as renewable energy utilization and the concepts and evaluation of recycling economy and eco-industrial parks.
With clear explanations, real-world examples and updated questions and answers, the tenth edition of Environmental Chemistry emphasizes the concepts essential to the practice of environmental science, technology and chemistry while introducing the newest innovations in the field. The author follows the general format and organization popular in preceding editions, including an approach based upon the five environmental spheres and the relationship of environmental chemistry to the key concepts of sustainability, industrial ecology and green chemistry. This readily adaptable text has been revamped to emphasize important topics such as the world water crisis. It details global climate change to a greater degree than previous editions, underlining the importance of abundant renewable energy in minimizing human influences on climate. Environmental Chemistry is designed for a wide range of graduate and undergraduate courses in environmental chemistry, environmental science and sustainability as well as serving as a general reference work for professionals in the environmental sciences and engineering.
Sustainable development, the circular economy and environmental issues are at the forefront of public and Government concern. The field of green chemistry aims to provide environmentally benign products from sustainable resources, using processes that do not harm people or the environment at the same time as helping solve key societal problems such as climate change. Updated throughout, this third edition features an expanded section on legislation, a revised chapter on measurement, and a completely re-written chapter on renewable resources, bringing readers the latest developments in this quickly-growing area. Case studies now include more recent examples of real-world applications from industry to demonstrate how the techniques of green chemistry work in practice. This fascinating textbook is suitable for undergraduate and postgraduate courses covering green chemistry, and it encourages new ways of thinking about how products and processes are developed.
In recent years the need for sustainable process design and alternative reaction routes to reduce industry?s impact on the environment has gained vital importance. The book begins with a general overview of new trends in designing industrial chemical processes which are environmentally friendly and economically feasible. Specific examples written by experts from industry cover the possibilities of running industrial chemical processes in a sustainable manner and provide an up-to-date insight into the main concerns, e.g., the use of renewable raw materials, the use of alternative energy sources in chemical processes, the design of intrinsically safe processes, microreactor and integrated reaction/ separation technologies, process intensification, waste reduction, new catalytic routes and/or solvent and process optimization.